Synopses & Reviews
Synopsis
Solvents have a major role to play in the environmental and sustainability agenda, and many currently used solvents have to be replaced, either because of regulations or because of increasing demands for safer solvents and produce them in safer way. Some solvents previously advertised as green solvents have to be replaced according to the present regulations, and these are costly and risky operations.
This book not only gives data on carefully selected, commercially available, green solvents but it also gives expert advice on how to assess and qualify green solvents. Physical properties are included, as are health and safety considerations (such as carcinogenicity, reproduction/developmental toxicity, flammability) and first aid guidance. Emphasis is given in particular to cost-saving and more efficient replacements for more toxic solvents.
Detailed information is also given for usage considerations, including outstanding properties, potential substitutes, features and benefits for each solvent and for which products the solvent is recommended.
- More than 300 green solvents included, from biodegradable and biorenewable solvents to siloxanes and perfluorocarbons.
- Practical information for use in the lab and the field, including recommended processing methods, recommended dosages, and potential substitutes
- Provides critical health, safety, and environmental data, to help production chemists and engineers in selecting the correct solvent.
Synopsis
Many currently used solvents have to be replaced, either because of regulations or because of ever growing trend to produce safer products or produce them in safer way. There is a lot of confusion in the market place regarding of what really consists of green solvent. Some solvents previously advertised as green solvents have to be replaced according to the present regulations, and these are costly and risky operations. The Databook of Green Solvents contains data divided into five sections: General, Physical, Health, Environmental, and Use. In the General section, the following data are displayed: Name, CAS number, Acronym, Chemical category, Empirical formula, IUPAC name, Mixture, Moisture contents, Molecular weight, Other properties, Product contents, EC number, RTECS number, and Synonyms 1, 2, 3. Physical section contains data on Dielectric constant, Acceptor number, Acid dissociation constant, Aniline point, Antoine temperature range, Antoine constants A, B, and C, Boiling temperature, Coefficient of thermal expansion, Color, Corrosivity, Donor number, Electrical conductivity, Evaporation rates with butyl acetate=1 and ether=1, Freezing temperature, Hansen solubility parameters dD, dP, and dH, Molar volume, Heat of combustion, Enthalpy of vaporization, Enthalpy of vaporization temperature, Henry's law constant, Hildebrand solubility parameter, Kauri butanol number, Odor, Odor threshold, pH, Polarity parameter, ET(30), Refractive index, Solubility in water, Specific gravity, Specific gravity temperature, Specific heat, State, Surface tension, Thermal conductivity, Vapor density, Vapor pressure, Vapor pressure temperature, Viscosity, and Viscosity temperature. Health section contains data on Autoignition temperature, Carcinogenicity: IRAC, NTP, OSHA, Mutagenic properties, Reproduction/developmental toxicity, DOT class, TDG class, ICAO/IATA class, packaging group, IMDG class, packaging group, UN/NA hazard class, UN packaging group, Proper shipping name, Explosion limits: lower and upper, Flash point, Flash point method, LD50 dermal (rabbit), LC50 inhalation (rat), LD50 oral (mouse), LD50 oral (rat), Maximum concentration during 30 min exposure (NIOSH-IDLH), Maximum concentration at any time: ACGIH, NIOSH, OSHA, Maximum concentration during continuous exposure for 15 min: ACGIH, NIOSH, OSHA, NFPA flammability, health, reactivity, Route of entry, Ingestion, Skin irritation, Eye irritation, Inhalation, First aid: eyes, skin, inhalation, Chronic effects, Target organs, Threshold limiting value: ACGIH, NIOSH, OSHA, UN number, UN risk phrases, and UN safety phrases. Environmental section contains data on Aquatic toxicity, Bluegill sunfish (96-h LC50), Daphnia magna (96-h LC50) and (48-h LC50), Fathead minnow (96-h LC50), Rainbow trout (96-h LC50), Bioconcentration factor, Biodegradation probability, Biological oxygen demand (20-day test) and (5-day test), Chemical oxygen demand, Atmospheric half-life, Hydroxyl rate constant, Global warming potential, Montreal protocol, Partition coefficient, Ozone depletion potential (CFC11=1), Ozone rate constant, Soil absorption constant, Theoretical oxygen demand, Urban ozone formation potential (C2H4=1), UV absorption. Use section contains information on Manufacturer, Outstanding properties, Potential substitutes, Recommended for polymers, Features & benefits, Processing methods, Recommended dosage, and Recommended for products. About 300 of the most essential solvents are included in the publication. Emphasis is given to safer and more efficient replacements of more toxic solvents. In addition to this publication, Databook of Solvents contains data on solvents most frequently used by industry. Readers interested in this subject should note that two volumes of fundamental treatment of all essential areas of solvents' use have also been just published. They include: Handbook of Solvents. Volume 1. Properties and Handbook of Solvents. Volume 2. Use, Health, and Environment.