This book covers a broad range of topics involving supercritical carbon dioxide from theoretical studies to applications in separations, materials science and reactivity and catalysis.
Contents Preface
Overview
1 An Introduction to Separations and Processes Using Supercritical Carbon Dioxide. Chien M. Wai, Aravamudan S. Gopalan, and Hollie K. Jacobs
Metals
2 Extraction of Uranium and Lanthanides from Their Oxides with a High-Pressure Mixture of TBP-HNO[3-H[20-CO[2. Youichi Enokida, Ichiro Yamamoto, and Chien M. Wai
3 Supercritical Fluid Extraction of Actinides and Heavy Metals for Environmental Cleanup: A Process Development Perspective. Yuehe Lin and Neil G. Smart
4 Supercritical Fluid Extraction of Plutonium and Americium from Soil Using *b-Diketone and Tributyl Phosphate Complexants. Robert V. Fox and Bruce Mincher
5 Solubility and Modifications of Metal Chelates in Supercrtical Carbon Dioxide. Bernd W. Wenclawiak, H. Beer, A. Ammann, and A. Wolf
6 Extracting Gold in Supercritical CO[2: Fluorinated Molecular Baskets and Thiourea Ligands for Au. Jeremy D. Glennon, Josephine Treacy, Anne M. O'Keeffe, Mark O'Connell, Conor C. McSweeney, Andrew Walker, and Stephen J. Harris
7 Ligand-Assisted Extraction of Metals from Fly Ash with Supercritical CO[2: A Comparison with Extraction in Aqueous and Organic Solutions. Christof Kersch, Daniela Trambitas, Geert F. Woerlee, and Geert J. Witkamp
Organics
8 Coupled Processing Options for Agricultural Materials Using Supercritical Fluid Carbon Dioxide. Jerry W. King
9 Supercritical Fluid Extraction of Bioactive Components from St. John's Wort ( Hypericum perforatum L.) and Ginko biloba . Mari Mannila, Qingyong Lang, Chien M. Wai, Yanyan Cui, and Catharina Y.W. Ang
10 Hot Water Extraction Followed by Solid-Phase Microextraction of Active Ingredients in Rosemary: An Organic Solvent-Free Analytical Technique. Youxin Gan and Yu Yang
11 Cleanup of Disperse Dye Contaminated Water by Supercritical Carbon-Dioxide Extraction. Jya-Jyun Yu and Kong-Hwa Chiu
12 Approaches to Soil Remediation with Green Procedures. Q. Wu, T. Yuan, and W.D. Marshall
Analytical and Modeling Methods
13 Time-Resolved Laser-Induced Fluorescence Characterization or Uranium Complexes and Processes in ScF CO[2. R. Shane Addleman and Chien Wai
14 Solubilization Study by QCM in Liquid and Supercritical CO[2 under Ultrasonar. Kwangheon Park, Moonsung Koh, Chunghyun Yoon, Hakwon Kim, and Hongdoo Kim
15 Uranyl Extraction by TBP from a Nitric Aqueous Solution to SC-CO[2: Molecular Dynamics Simulations of Phase Demixing and Interfacial Systems. Rachel Schurhammer and Georges Wipff
16 Experimental Measurement and Modeling of the Vapor-Liquid Equilibrium of *b-Diketones with CO[2. Chris Lubbers, Aaron M. Scurto, and Joan F. Brennecke
17 Thermodyanmics of Bayliss-Hillman Reaction in Supercritical Carbon Dioxide. Anthony A. Clifford, Paul M. Rose, Katherine Lee, and Christopher M. Rayner
Novel Materials
18 Dissolving Carbohydrates in CO[2: Renewable Materials as CO[2-philes. Poovathinthodiyil Raveendran and Scott L. Wallen
19 Design and Performance of Surfactants for Carbon Dioxide. Julian Eastroe, Audrey Dupont, Alison Paul, David C. Steytler, and Emily Rumsey
20 Nanoparticle Formation in Rapid Expansion of Water-in-Carbon Dioxide Microemulsion into Liquid Solvent. Mohammed J. Meziani, Pankaj Pathak, Lawrence F. Allard, and Ya-Ping Sun
21 Fine Particle Pharmaceutical Manufacturing Using Dense Carbon Dioxide Mixed with Acqueous or Alcholic Solutions. Edward T.S. Huang, Hung-yi Chang, C.D. Liang, and R.E. Sievers
22 Nanocrystal Synthesis and Stabilization in Supercritical Solvents. Parag S. Shah, Keith P. Johnston, and Brian A. Korgel
23 Supercritical Melt Miconization Using the Particles from Gas-Saturated Solution Process.
24 Synthesis of Nanostructured Sorbent Materials Using Supercritical Fluids. Thomas S. Zemanian, Glen E. Fryxell, Oleksey Ustyugov, Jerome C. Birnbaum, and Yuehe Lin
25 Synthesis of Structured Polymeric Materials Using Compressed Fluid Solvents. A.I. Cooper, R. Butler, C.M. Davies. A.K. Hebb, K. Senoo, and C.D. Wood
Reactions in Supercritical Carbon Dioxide
26 Catalytic Hydrogenation of Olefins in Supercritical Carbon Dioxide Using Rhodium Catalysts Supported on Fluroacrylate Copolymers. Roberto Flores, Zulema K. Lopez-Castillo, Aydin Akgerman, Ibrahim Kani, and John P. Fackler, Jr.
27 Hydrogenation Reactions in Supercritical CO[2 Catalyzed by Metal Nanoparticles in a Water-in-Carbon Dioxide Microemulsions. Xing Dong and Can Erkey
Indexes
Author Index
Subject Index